Living radical polymerisation
Convener:
Dave Haddleton, University of Warwick, UK
Co-Convener: Sebastien Perrier, University of Sydney, Australia
Co-Convener: Giuseppe Mantovani, University of Nottingham, UK
Programme:
Monday 12 July (afternoon)
Tuesday 13 July (morning and afternoon)
Wednesday 14 July (morning)
Symposium Information
- Transition metal mediated radical polymerisation, ATRP and SET-LRP.
- Reversible addition fragmentation transfer (RAFT) polymerisation.
- Stable free radical polymerisation.
- Mechanisms, kinetics and novel properties.
- Novel polymer architectures form stars and hyperbranched to multi-block copolymers and surface initiation.
- Scale up and commercialisation aspects.
This symposium will cover all aspects of living and controlled radical polymerisation. Aspects of all types of this class of polymerisation reaction will be covered including ATRP, RAFT, SFRP and newer emerging chemistry such as SET LRP. We will be looking to have an in depth discussion of mechanistic aspects and seeing where there is overlap and also distinction. Following on from this the symposium will cover the different types of polymer architecture available which will also touch on characterisation issues. The different polymers available will then be used to illustrate the wide range of application being looked at from polymer therapeutics to viscosity modifiers. We will be seeking to involve industrial contributions here. The symposium will conclude with issues around scale up and commercialisation of this technology.
Keynote Speakers
ATRP- from mechanism to materials
Krzysztof Matyjaszewski, Carnegie Mellon University, USA
Self-Controlled Supramolecular and Living Radical Polymerizations
Virgil Percec, University of Pennsylvania, USA
Invited Speakers
Synthesis of Biomolecule-Reactive Telechelic Polymers Using Controlled Radical Polymerizations and Therapeutic Applications of the Resulting Protein Dimer-Polymer Conjugates
Heather Maynard, University of California, Los Angeles, USA
Designing Nanostructured Materials with Peptide-Polymer Conjugates
Sebastien Perrier, University of Sydney, Australia
Title TBC
Alan Rowan, Radboud University, The Netherlands
Metal-Catalyzed Living Radical Polymerization for the Precision Synthesis of Functional Macromolecules
Mitsuo Sawamoto, Kyoto University, Japan
Speakers
Synthesis of Sterically-Stabilized Nanolatexes by Living Radical Polymerization
Steven Armes, University of Sheffield, UK
Synthesis of N-acryloxysuccinimide based homo- and co-polymers by nitroxide mediated polymerization
Denis Bertin, Université de Provence, France
Phenanthrene and Rhodamine-B derived RAFT agents. Synthesis of alpha-end-functionalized thermosensitive polymers and fluorescence studies
Marie-Therese Charreyre, ENS, France
Some recent advances in the MADIX process
Mathias Destarac, Université Paul Sabatier, France
Development of Photosensitive Alkoxyamines for Nitroxide Mediated PhotoPolymerization
Didier Gigmes, Université de Provence, France
Controlled Dispersion Polymerisation in Supercritical Carbon Dioxide: Designing scCO2 Stabilisers and Preparing Living Block Co-Polymer Microparticles
Steve Howdle, University of Nottingham, UK
Anionic Polymerizability of N,N-Dialkylmethacrylamides
Takashi Ishizone, Tokyo Institute of Technology, Japan
Novel amphiphilic block copolymers and conetworks by combining click chemistry, quasiliving atrp and carbocationic polymerizations
Bela Ivan, Hungarian Academy of Science, Hungary
Control of Molecular Weight using the Reverse Iodine Transfer Polymerization (RITP)- Emulsion Technique
Gijung Kim, Inha University, Korea
Controlled Photopolymerization of n-Butyl Methacrylate in Microemulsion Mediated by HO-TEMPO
Xiaoxuan Liu, Guangdong University of Technology, China
Investigating Polymer Structure by Gel Permeation Chromatography
Ben MacCreath, Varian, Inc., UK
Development and Application of Switchable RAFT agents
Graeme Moad, CSIRO, Australia
Synthesis of stimuli-responsive block copolymers based on poly(N,N-diethylacrylamide) by RAFT polymerization
Sophie Monge, Université Montpellier II, France
System Design toward Sequence Regulated Polymerization
Makoto Ouchi, Kyoto University, Japan
Magnetic Nanotechnology applied to Controlled Radical Polymerization
Ron Sanderson, Stellenbosch University, South Africa
Controlled Radical Polymerization of Vinyl Acetate Mediated by a Vanadium Catalyst
Michael Shaver, University of Prince Edward Island, Canada
Self Healing Polymers Prepared via Living Radical Polymerisation
Jay Syrett, University of Warwick, UK
Compartmentalized Designer Catalysts via Living Radical Polymerization
Takaya Terashima, Eindhoven University of Technology, The Netherlands
Precisely Synthesised Hollow Polymer Nanocapsules
Michael Whittaker, University of New South Wales, Australia
Single-electron Transfer Living Radical Polymerization (SET-LRP) of Methyl Methacrylate (MMA) with a Typical RAFT Agent as An Initiator
Zhengbiao Zhang, Soochow University, China
Poster Presenters
Making Well-Defined Macromolecules with Nitrone End Groups
Edgar H. H. Wong, University of New South Wales, Australia
Theoretical investigation of polycyclic saturated tetrazine: a breakthrough to 1,2,4,5-tetrazine
Pravat Kumar Swain, IIT Delhi, India
Lectin recognizable Biomaterials synthesized via Nitroxide Mediated Controlled Free-Radical Polymerization of a Methacryloyl Galactose Monomer
Maud Save, CNRS-University of Pau, France
Investigations on Different Verdazyl Derivatives for a Controlled Living Radical Polymerisation
Georgina Rayner, University of Warwick, United Kingdom
Utilization of Nitrones in Polymer Synthesis: Molecular Weight Control, Blockcopolymers and Polymer Conjugation
Thomas Junkers, Universiteit Hasselt, Belgium
New Polymer Synthesis by Controlling the Kinetic Process of ATRP of AB* Inimers
Zi-Chen Li, Peking University, China
Emulsion Polymerization of Methyl Methacrylate using the Reverse Iodine Transfer Polymerization (RITP) Technique
Eunhee Kim, Inha University, Korea, Republic of
Determination of the Rate Coefficients Associated with the RAFT Equilibrium via Time-Resolved EPR Spectroscopy after Laser Pulse Initiation
Wibke Meiser, Georg-August-Universität Göttingen, Germany
Microwave-Assisted Nitroxide-Mediated Radical Polymerization of Acrylamide in Aqueous Solution
Julien Rigolini, Université de Pau, France
Synthesis and Characterization of the ( n-BA)-b-St Copolymers by Photopolymerization of NMP/ATRP Technique using Macroinitiator in the Microemulsion
Xiaoxuan Liu, Guangdong University of Technology, China
A Low Temperature Alkoxyamine Designed for Use in Nitroxide-Mediated Miniemulsion Polymerization
Bencha Thongnuanchan, The University of Manchester, United Kingdom
Quantitative Investigation of The Effect of AIBN on Polymer-end Structure in Organoheteroatom-mediated Living Radical Polymerization
Yasuyuki Nakamura, Kyoto University, Japan
New Hydrocarbon Surfactants for Dispersion Polymerisation in scCO2
Nicholas Arrowsmith, University of Nottingham, United Kingdom
Water-Soluble Organo-Silica Hybrid Nanotubes Templated by Cylindrical Polymer Brushes
Markus Müllner, University of Bayreuth, Germany
New Metal Complexes for Radical Polymerization of Vinyl Monomers
Regina Islamova, Institute of Organic Chemistry of Ufa Scientific Centre of the Russian Academy of Sciences, Russian Federation
Design of functionalized PEG-based polymers by nitroxide-mediated polymerization for bioconjugation purposes
Julien Nicolas, Université Paris-Sud 11, France
Glycopolymer Grafted Microspheres
André Pfaff, University of Bayreuth, Germany
Smart Hydrogels based on star-shaped diblock copolymers of N,N'-dialkylaminoethyl methacrylates
Alexander Schmalz, University of Bayreuth, Germany
Chemical Modification of Polyaniline by N-Grafting of Polyethylacrylate Synthesized via ATRP
Bakhshali Massoumi, Payame Noor University, Iran, Islamic Republic of
Facing the problem of the bis(acetylacetonato)cobalt(II)-mediated radical polymerization of acrylates
Marie Hurtgen, University of Ličge, Belgium
Modified polydopamine-melanin coatings as initiators for surface-initiated ATRP
Bocheng Zhu, Loughborough University, United Kingdom
Toward Sequence Regulated Polymerization: Selective Radical Reactions with Designed Template Initiators
Shohei Ida, Kyoto University, Japan
Tandem Catalysis for Living Radical Polymerization and Transesterification: Precision Syntheses of Gradient Copolymers
Kazuhiro Nakatani, Kyoto University, Japan
The ESARA Process: A Bridge between Nitroxide-Mediated and RAFT Controlled Radical Polymerization Techniques
Arnaud Favier, UMR 5223 CNRS and USR3010 CNRS-ENS Lyon, France
Star Polymers via Cross-Linking Linear Poly(amino acid) Macromonomers by (Controlled) Radical Polymerization
Fabrice Audouin, Dublin City University, Ireland
Designing new functional and responsive amino polymers via RAFT polymerisation
Pepa Cotanda, University of Warwick, United Kingdom
Ring-Opening Polymerization of 1,3-Dehydroadamantanes
Sotaro Inomata, Tokyo Institute of Technology, Japan
Synthesis of Photoactive Polymer Matrices for Gold Nanoparticles as Non-Linear Optic Antennae
Ulrike Georgi, Leibniz Institut für Polymerforschung Dresden e.V., Germany
Polymerization of 2-Hydroxyethyl Methacrylate Catalyzed by Cyclometalated RuII Compounds
Maria-Ortencia Gonzalez, Instituto de Investigaciones en Materiales, Mexico
Evaluation of the Catalytic Activity of Cyclometalated-Ruthenium(II) Complex in the Polymerization of Styrene and Methyl Methacrylate
Vanessa Martinez Cornejo, Universidad Nacional Autonoma de México, Mexico
Synthesis and use of a new alkene-functionalized SG1-based alkoxyamine
Claire Bernhardt, Université Pierre et Marie Curie (Paris VI), France
Atom Transfer Radical Polymerization (ATRP) copolymers in combination with gemini surfactants as diesel fuel wax dispersants
Norah Maithufi, Sasol Technology, South Africa
Comb-type copolymers prepared via Atom Transfer Radical Polymerization as potential cold flow improvers in GTL diesel fuels
Norah Maithufi, Eindhoven University of Technology, Netherlands
Surface-Initiated Polymerization and Characterization of Mixed Polymer Brushes of Poly( N-isopropylacrylamide) and Poly(methacrylic acid) on Gold
Xiaofeng Sui, University of Twente, Netherlands
Controlled polymerisation of sulfonate-containing monomers via Atom Transfer Radical Polymerisation
Darren Campbell, Aston University, United Kingdom
Polymeric Membranes for the Treatment and Purification of Water
Catherine Fox, National University of Ireland Maynooth, Ireland
A New Phosphine Oxide as Catalyst for Reversible Chain Transfer Catalyzed Polymerization (RTCP)
Arne Wolpers, Institute of Physical Chemistry, Göttingen, Germany
Synthesis and Characterisation of a six-arm star poly(styrene sulfonate) containing alpha-cyclodextrin core
Haruna Musa, Bayero University Kano, Nigeria
Preparation and Physical Properties of Copolymer based Carbon Nanotube Composites Prepared by 'Double Percolation' By Means of Controlled Radical Polymerisation in a Latex Using Reverse Addition Fragmentation Transfer Polymerisation and Reverse Atom Transfer Radical Polymerisation
Gavin T H Hill, Free University of Brussels, Belgium
Symposium Sponsor
