Metal–ligand bonding
Rob Janes and Elaine Moore
Cambridge: RSC–OU 2004 | Pp108 | 24.95 | ISBN0 854 04979 7
Reviewed by C. F. Murray

This textbook describes the theory of transition metal–ligand bonding, essential to an understanding of the chemistry and physical properties of transition metal complexes. Designed to form the foundation of an undergraduate module on d-block chemistry, the book is more suitable for second- and third-year undergraduates since a basic knowledge of atomic and molecular orbitals as applied to Main Group elements is assumed.

The text is written in an accessible, detailed, non-mathematical manner and is a joy to read. Initial chapters detail electronic configuration of d-electrons on metal ions, followed by the crystal-field theory. Subsequent chapters use this theory to account for the variation in physical properties such as ionic radii and to describe the applications of magnetic measurements to distinguish complexes with different electronic configurations and structures. The extensive coverage includes electronic spectra, magnetic properties, molecular orbital theory using a pictorial approach, and bonding in different geometric complexes. Most chapters include clear, colour diagrams, questions with answers, revision exercises and clearly defined learning outcomes to encourage a reflective approach to study.

An associated website, experimental data and interesting observations from everyday life complete this excellent publication. Priced at £24.95, Metal–ligand bonding is good value for money and should be required reading for all undergraduate chemists.