Issue 5, 1986
From the journal:

Journal of the Chemical Society, Chemical Communications

Electronic structure of bis(cyclopentadienyl) lanthanide compounds: photoelectron spectra and molecular orbital calculations

Richard A. Andersen,   James M. Boncella,   Carol J. Burns,   Jennifer C. Green,   Detlef Hohl  and  Notker Rösch  

Abstract

Gas phase He-I and He-II photoelectron (p.e.) spectra have been obtained for Ln(η-C5Me5)2, where Ln = Sm, Eu, Yb, and bands associated with ionization of f-electrons are identified for the Sm and Yb compounds; ionization energies calculated from quasi-relativistic Xα-SW calculations are in good agreement with the experimental values showing the compounds to be highly ionic in nature, but providing no orbital reason for the established non-parallel geometry of the rings.

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Article information

DOI
https://doi.org/10.1039/C39860000405
Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 405-407

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Electronic structure of bis(cyclopentadienyl) lanthanide compounds: photoelectron spectra and molecular orbital calculations

R. A. Andersen, J. M. Boncella, C. J. Burns, J. C. Green, D. Hohl and N. Rösch, J. Chem. Soc., Chem. Commun., 1986, 405 DOI: 10.1039/C39860000405

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