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Journal of the Chemical Society, Chemical Communications


Journal of the Chemical Society, Chemical Communications was published between 1972 - 1995.

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Paper

J. Chem. Soc., Chem. Commun., 1995, 2473 - 2474, DOI: 10.1039/C39950002473


Phosphine-mediated [2 + 2] cycloaddition of internal alk-2-ynoate and alk-2-ynone to [60]fullerene

Kou-Fu Liou and Chien-Hong Cheng


Treatment of RCH2CCCOX with [60]fullerene in the presence of tricyclohexylphosphine (PCy3) afforded a [2 + 2] cycloaddition product (1: R = H, X = OMe); 2: R = Bu, X = OMe; 3: R = X = Me which resulted from addition of the , -carbons of RCH2CCCOX to the carbon-carbon double bond across a 6/6 ring junction of [60]fullerene.