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Journal of the Chemical Society, Chemical Communications


Journal of the Chemical Society, Chemical Communications was published between 1972 - 1995.

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Paper

J. Chem. Soc., Chem. Commun., 1995, 2485 - 2486, DOI: 10.1039/C39950002485


Mutual isomerization of 1-allenyl and 1-propargyl complexes of platinum via a five-coordinate 3-allenyl/propargyl intermediate

Sensuke Ogoshi, Yoshiaki Fukunishi, Ken Tsutsumi and Hideo Kurosawa


The reversible spontaneous isomerization between 1-allenyl and 1-propargylplatinum complexes is reported, which is suggested to proceed via pseudorotation of a five-coordinate 3-allenyl/propargyl intermediate.