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Journal of the Chemical Society, Chemical Communications


Journal of the Chemical Society, Chemical Communications was published between 1972 - 1995.

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Paper

J. Chem. Soc., Chem. Commun., 1995, 2499 - 2500, DOI: 10.1039/C39950002499


Switching of two amine ligands via an SN2-type mechanism in a coordinated form of 2,6-bis(N,N-dimethylaminomethyl)phenylboronates

Shinji Toyota, Tadahiro Futawaka, Hiroshi Ikeda and Michinori ki


Facile exchange between the intramoleculariy coordinated and uncoordinated amine ligands in the title compounds is evidenced by NMR spectroscopy in solution, whereas the dynamic process is frozen in the solid phase as shown by X-ray crystallography.