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Journal of the Chemical Society, Chemical Communications


Journal of the Chemical Society, Chemical Communications was published between 1972 - 1995.

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Paper

J. Chem. Soc., Chem. Commun., 1995, 2533 - 2534, DOI: 10.1039/C39950002533


Preparation of zeolites incorporating molybdenum sulfide clusters with high C2 hydrocarbon selectivity in Co–H2 reactions

Mitsugu Taniguchi, Youichi Ishii, Takashi Murata, Takashi Tatsumi and Masanobu Hidai


The incomplete cubane-type cluster, [Mo3S4(H2O)9]4+, and the complete cubane-type cluster, [Mo3NiS4(H2O)9Cl]3+, are incorporated into 12-membered ring zeolites by ion exchange, leading to catalysts which are highly selective for C2 formation from CO–H2.