Journal of the Chemical Society, Chemical Communications
Journal of the Chemical Society, Chemical Communications was published between 1972 - 1995.
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Paper
J. Chem. Soc., Chem. Commun., 1995, 2549 - 2550, DOI: 10.1039/C39950002549
Probing the onset of crystallization of a microporous catalyst by combined X-ray absorption spectroscopy and X-ray diffraction
Gopinathan Sankar, John Meurig Thomas, Fernando Rey and G. Neville Greaves
The power of a new variant of the in situ combined XRA-XRD experiment (see ref. 12) is illustrated by tracking the inner shell environment and bonding of a CoIIion as it changes, in the gel just prior to crystallisation, from octahedral to tetrahedral coordination, the state in which it finally appears in the microporcus catalyst CoAlPO-5: the technique is widely applicable.
