Issue 1, 2000
From the journal:

Chemical Communications

Total spontaneous resolution of a cyanoguanidine showing only conformational chirality

Ian D. Cunningham,*a   Simon J. Colesb  and  Michael B. Hursthouseb  

* Corresponding authors

a Department of Chemistry, School of Physics and Chemistry, University of Surrey, Guildford, UK
E-mail: i.cunningham@surrey.ac.uk

b Department of Chemistry, University of Southampton, Highfield, Southampton, UK

Abstract

The total spontaneous resolution of N-(4-chlorophenyl)-N′-cyano-N,N″ ,N″-trimethylguanidine, a compound which shows only conformational chirality, is described; variable temperature NMR experiments show that rotation of the dimethylamino group is rapid in solution at room temperature as is conformer interconversion by rotation of the arylmethylamino group.

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Article information

DOI
https://doi.org/10.1039/A907518F
Article type
Communication
Submitted
16 Sep 1999
Accepted
23 Nov 1999
First published
06 Jan 2000

Chem. Commun., 2000, 61-62

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Total spontaneous resolution of a cyanoguanidine showing only conformational chirality

I. D. Cunningham, S. J. Coles and M. B. Hursthouse, Chem. Commun., 2000, 61 DOI: 10.1039/A907518F

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