Issue 7, 2000
From the journal:

Chemical Communications

Synthesis of medium-ring lactones via tandem methylenation/Claisen rearrangement of cyclic carbonates

James E. P. Davidson,a   Edward A. Anderson,a   Wilm Buhr,a   Justin R. Harrison,a   Paul T. O’Sullivan,a   Ian Collins,b   Richard H. Greenc  and  Andrew B. Holmes*a  

* Corresponding authors

a Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, UK
E-mail: abh1@cus.cam.ac.uk

b Merck Sharp and Dohme Research Laboratories, Neuroscience Research Centre, Terlings Park, Harlow, UK

c Exploratory Chemistry, Glaxo Wellcome Research & Development, Medicines Research Centre, Gunnels Wood Road, Stevenage, UK

Abstract

Tandem methylenation/Claisen rearrangement of cyclic carbonates derived from vinyl-substituted 1,3- and 1,4-diols afforded eight and nine-membered unsaturated lactones respectively.

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Article information

DOI
https://doi.org/10.1039/B000299M
Article type
Communication
Submitted
06 Jan 2000
Accepted
04 Feb 2000
First published
22 Mar 2000

Chem. Commun., 2000, 629-630

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Synthesis of medium-ring lactones via tandem methylenation/Claisen rearrangement of cyclic carbonates

J. E. P. Davidson, E. A. Anderson, W. Buhr, J. R. Harrison, P. T. O’Sullivan, I. Collins, R. H. Green and A. B. Holmes, Chem. Commun., 2000, 629 DOI: 10.1039/B000299M

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