Issue 17, 2000
From the journal:

Chemical Communications

Room temperature formation of rhodium nanoparticles on TiO2[110] via MetalOrganic Chemical-Vapour Deposition (MOCVD) of [Rh(CO)2Cl]2

Mark A. Newton,*a   Roger A. Bennett,*b   Rupert D. Smith,b   Michael Bowkerb  and  John Evansa  

* Corresponding authors

a Department of Chemistry, University of Southampton, Highfield, Southampton, UK
E-mail: m.a.newton@soton.ac.uk

b Centre for Surface Science and Catalysis, Department of Chemistry, University of Reading, Whiteknights Park, Reading, UK
E-mail: r.a.bennett@reading.ac.uk

Abstract

Room temperature adsorption of [Rh(CO)2Cl]2 on TiO2[110] is investigated using Scanning Tunnelling Microscopy (STM) which reveals the formation of nanoparticles that coexist with the mono-disperse Rh(CO)2Cl species; the spatial distribution of these particles indicates that nanoparticle formation occurs principally at step edges.

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Article information

DOI
https://doi.org/10.1039/B003782F
Article type
Communication
Submitted
11 May 2000
Accepted
25 Jul 2000
First published
16 Aug 2000

Chem. Commun., 2000, 1677-1678

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Room temperature formation of rhodium nanoparticles on TiO2[110] via MetalOrganic Chemical-Vapour Deposition (MOCVD) of [Rh(CO)2Cl]2

M. A. Newton, R. A. Bennett, R. D. Smith, M. Bowker and J. Evans, Chem. Commun., 2000, 1677 DOI: 10.1039/B003782F

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