Issue 19, 2000

RbCuPO4 – a maximum copper tetrahedral framework adopting the zeotype ABW structure

Abstract

The sky blue RbCuPO4-ABW is the first reported maximum copper (framework ratio 1∶1) zeotype framework, consisting of alternating PO4 and flattened CuO4 (Cu–O 1.89–1.95 Å) tetrahedra; a second metastable very pale green–blue phase can also be produced by quenching, with conversion to the purely four-coordinate copper material accomplished by application of slight mechanical pressure.

Article information

Article type
Communication
Submitted
07 Aug 2000
Accepted
05 Sep 2000
First published
21 Sep 2000

Chem. Commun., 2000, 1959-1960

RbCuPO4 – a maximum copper tetrahedral framework adopting the zeotype ABW structure

P. F. Henry, R. W. Hughes, S. C. Ward and M. T. Weller, Chem. Commun., 2000, 1959 DOI: 10.1039/B006429G

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