Issue 23, 2006
From the journal:

Chemical Communications

Synthesis and crystal structure of Li4BH4(NH2)3†

Philip A. Chater,a   William I. F. David,*bc   Simon R. Johnson,c   Peter P. Edwardsc  and  Paul A. Anderson*a  

* Corresponding authors

a School of Chemistry, The University of Birmingham, Edgbaston, Birmingham, UK
E-mail: p.a.anderson@bham.ac.uk

b ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, Oxon., UK
E-mail: W.I.F.David@rl.ac.uk

c Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, UK
E-mail: peter.edwards@chemistry.oxford.ac.uk

Abstract

The solid solution, (LiNH2)x(LiBH4)(1−x), formed through the reaction of the two potential hydrogen storage materials, LiNH2 and LiBH4, is dominated by a compound that has an ideal stoichiometry of Li4BN3H10 and forms a body-centred cubic structure with a lattice constant of ca. 10.66 Å.

Graphical abstract: Synthesis and crystal structure of Li4BH4(NH2)3

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Article information

DOI
https://doi.org/10.1039/B518243C
Article type
Communication
Submitted
23 Dec 2005
Accepted
30 Jan 2006
First published
16 Feb 2006

Chem. Commun., 2006, 2439-2441

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Synthesis and crystal structure of Li4BH4(NH2)3

P. A. Chater, W. I. F. David, S. R. Johnson, P. P. Edwards and P. A. Anderson, Chem. Commun., 2006, 2439 DOI: 10.1039/B518243C

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