Issue 16, 2006

Bisphosphine based hetero-capsules for the encapsulation of transition metals

Abstract

Just mixing of solutions of tetracationic diphosphine ligands and tetraanionic calix[4]arene building blocks leads to the formation of supramolecular heterocapsules that coordinate a palladium metal within the cavity of the assembly, giving rise to a new class of potential supramolecular transition metal catalysts.

Graphical abstract: Bisphosphine based hetero-capsules for the encapsulation of transition metals

Supplementary files

Article information

Article type
Communication
Submitted
03 Jan 2006
Accepted
09 Jan 2006
First published
24 Jan 2006

Chem. Commun., 2006, 1700-1702

Bisphosphine based hetero-capsules for the encapsulation of transition metals

T. S. Koblenz, H. L. Dekker, C. G. de Koster, P. W. N. M. van Leeuwen and J. N. H. Reek, Chem. Commun., 2006, 1700 DOI: 10.1039/B518274C

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