Issue 27, 2006
From the journal:

Chemical Communications

Reversible lithium insertion and copper extrusion in layered oxysulfides†

Oliver J. Rutt,a   Gareth R. Williamsa  and  Simon J. Clarke*a  

* Corresponding authors

a Department of Chemistry, University of Oxford, Inorganic Chemistry Laboratory, South Parks Road, Oxford, UK
E-mail: simon.clarke@chem.ox.ac.uk
Fax: +44 1865 272690
Tel: +44 1865 272600

Abstract

All of the copper in the layered oxysulfides Sr2MnO2Cu1.5S2 and Sr2MnO2Cu3.5S3 may be extruded as the element and the copper ions replaced quasi-reversibly by lithium ions in reductive topotactic ion exchange reactions; dramatic changes in magnetic properties result.

Graphical abstract: Reversible lithium insertion and copper extrusion in layered oxysulfides

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Article information

DOI
https://doi.org/10.1039/B605105G
Article type
Communication
Submitted
10 Apr 2006
Accepted
10 May 2006
First published
06 Jun 2006

Chem. Commun., 2006, 2869-2871

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Reversible lithium insertion and copper extrusion in layered oxysulfides

O. J. Rutt, G. R. Williams and S. J. Clarke, Chem. Commun., 2006, 2869 DOI: 10.1039/B605105G

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