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Communication
Chem. Commun., 2006, 4081 - 4083, DOI: 10.1039/b606736k
High pressure co-ordination chemistry of a palladium thioether complex: pressure versus electrons
David R. Allan, Alexander J. Blake, Deguang Huang, Timothy J. Prior and Martin Schröder
The mononuclear Pd(II) complex cis-[PdCl2([9]aneS3)]([9]aneS3= 1,4,7-trithiacyclononane) converts at 44 kbar pressure into an intensely coloured chain polymer, which exhibits distorted octahedral co-ordination at the metal centre and an unprecedented [1233] conformation for the thioether crown.
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