Issue 47, 2006
From the journal:

Chemical Communications

[Cu(HF2)(pyz)2]BF4 (pyz = pyrazine): long-range magnetic ordering in a pseudo-cubic coordination polymer comprised of bridging HF2− and pyrazine ligands†

Jamie L. Manson,*a   Marianne M. Conner,a   John A. Schlueter,b   Tom Lancaster,c   Stephen J. Blundell,c   Michael L. Brooks,c   Francis L. Pratt,d   Thomas Papageorgiou,e   Andreas D. Bianchi,e   Jochen Wosnitzae  and  Myung-Hwan Whangbof  

* Corresponding authors

a Department of Chemistry and Biochemistry, Eastern Washington University, Cheney, WA 99004, USA
E-mail: jmanson@ewu.edu
Fax: 509-359-6973
Tel: 509-359-2878

b Materials Science Division, Argonne National Laboratory, Argonne, IL 60439, USA

c Clarendon Laboratory, Physics Department, Oxford University, Oxford, UK

d ISIS Facility, Rutherford-Appleton Laboratory, Chilton, Didcot, UK

e Hochfeld-Magnetlabor Dresden (HLD), Forschungszentrum Rossendorf, D-01314 Dresden, Germany

f Department of Chemistry, North Carolina State University, Raleigh, NC 27695, USA

Abstract

[Cu(HF2)(pyz)2]BF4 consists of rare μ1,3 bridging HF2− anions and μ-pyrazine ligands leading to a 3D pseudo-cubic framework that antiferromagnetically orders below 1.54(1) K.

Graphical abstract: [Cu(HF2)(pyz)2]BF4 (pyz = pyrazine): long-range magnetic ordering in a pseudo-cubic coordination polymer comprised of bridging HF2− and pyrazine ligands

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Article information

DOI
https://doi.org/10.1039/B608791D
Article type
Communication
Submitted
21 Jun 2006
Accepted
02 Aug 2006
First published
22 Aug 2006

Chem. Commun., 2006, 4894-4896

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[Cu(HF2)(pyz)2]BF4 (pyz = pyrazine): long-range magnetic ordering in a pseudo-cubic coordination polymer comprised of bridging HF2− and pyrazine ligands

J. L. Manson, M. M. Conner, J. A. Schlueter, T. Lancaster, S. J. Blundell, M. L. Brooks, F. L. Pratt, T. Papageorgiou, A. D. Bianchi, J. Wosnitza and M. Whangbo, Chem. Commun., 2006, 4894 DOI: 10.1039/B608791D

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