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Chem. Commun., 2007, 4644 - 4646, DOI: 10.1039/b710677g

Cobalt-catalyzed intermolecular C–H amination with bromamine-T as nitrene source

Jeremiah D. Harden, Joshua V. Ruppel, Guang-Yao Gao and X. Peter Zhang

Cobalt, supported by porphyrin ligands, is capable of catalyzing intermolecular nitrene insertion of sp3 C–H bonds with bromamine-T as the nitrene source, forming the desired tosyl-protected amines with NaBr as the by-product.

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