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Communication

Chem. Commun., 2007, 4006 - 4008, DOI: 10.1039/b712322a


Uranyl stabilized Schiff base complex

Mohan S. Bharara, Stephen A. Tonks and Anne E. V. Gorden


Uranyl Schiff base complex [(UO2)2(Salpro)(OH)(Solvent)2] ( 1) in the presence of excess of ethylenediamine (EDA) does not undergo nucleophilic addition (hydrolysis) and substitution (transamination) reactions due to an extended chelation [2N, 3O + OH] by the flexible backbone.

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