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Communication

Chem. Commun., 2008, 1635 - 1637, DOI: 10.1039/b716879a

Mutual induced coordination in halogen-bonded anionic assemblies with (6,3) cation-templated topologies

Pierangelo Metrangolo, Frank Meyer, Tullio Pilati, Giuseppe Resnati and Giancarlo Terraneo

We describe the use of halogen bonding for the deliberate construction of cation-templated anionic (6,3) networks thanks to a strategy based on the mutual induced fitting of the valences of the building blocks.

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