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Chem. Commun., 2008, 1413 - 1415, DOI: 10.1039/b719384j


Ultraselective fluorescent sensing of Hg2+ through metal coordination-induced molecular aggregation

Yanke Che, Xiaomei Yang and Ling Zang


A new type of fluorescent sensor has been developed from a perylene based molecule, N,N-dideoxythymidine-3,4,9,10-perylene-tetracarboxylic diimide (TT-PTCDI); the strong, highly selective binding between the thymine ligand (T) and Hg2+ ion enables efficient sensing of mercury ions based on a fluorescence quenching mechanism, which is primarily caused by metal-coordination induced molecular aggregation.

Graphical abstract image for this article  (ID: b719384j)