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Chem. Commun., 2008, 1926 - 1928, DOI: 10.1039/b801597j

An unusual dianion equivalent from acylsilanes for the synthesis of substituted -keto esters

Chris V. Galliford and Karl A. Scheidt

The reaction of lithiated diazo esters with acylsilanes generates a remarkable intermediate en route to highly substituted -keto esters.

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