Issue 30, 2008
From the journal:

Chemical Communications

Convenient method for the rapid generation of highly active and enantioselective yttrium catalysts for asymmetric hydroamination†

Jérôme Hannedouche,*a   Isabelle Aillaud,a   Jacqueline Collin,*a   Emmanuelle Schulza  and  Alexander Trifonovb  

* Corresponding authors

a Equipe de Catalyse Moléculaire, ICMMO, UMR CNRS 8182, Université Paris Sud 11, Bat 420, Orsay Cedex, France
E-mail: jacollin@icmo.u-psud.fr; jerome.hannedouche@icmo.u-psud.fr
Fax: 33(0)169154680
Tel: 33(0)169154740

b G. A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences, Tropinia 49, Nizhny Novgorod GSP-445, Russia

Abstract

A facile method for the preparation of highly active and enantioselective yttrium precatalysts for asymmetric hydroamination of gem-disubstituted aminoalkenes, from the combination of YCl3 or YCl3(THF)3.5 with ligand (R)-L1 and n-BuLi is described.

Graphical abstract: Convenient method for the rapid generation of highly active and enantioselective yttrium catalysts for asymmetric hydroamination

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Article information

DOI
https://doi.org/10.1039/B804745F
Article type
Communication
Submitted
19 Mar 2008
Accepted
22 Apr 2008
First published
02 Jun 2008

Chem. Commun., 2008, 3552-3554

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Convenient method for the rapid generation of highly active and enantioselective yttrium catalysts for asymmetric hydroamination

J. Hannedouche, I. Aillaud, J. Collin, E. Schulz and A. Trifonov, Chem. Commun., 2008, 3552 DOI: 10.1039/B804745F

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