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Communication
Chem. Commun., 2008, 3648 - 3650, DOI: 10.1039/b804754e
Reactivity of a Co(I) [N2P2] complex with azides: evidence for a transient Co(III) imido species
Wayne A. Chomitz and John Arnold
The synthesis of a monomeric Co(I) complex supported by a multidentate monoanionic [N2P2] ligand is described; interaction with aryl azides at low temperature generates a species whose reactivity is consistent with imido (
Co
NR
) character.
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