Issue 7, 2009
From the journal:

Chemical Communications

Benzo-1,3,2-diazaphospholide and benzo-1,3,2-diazaphospholium: an isoelectronic aromatic anion–cation pair†

Dirk Schmid,a   Sebastian Loscher,a   Dietrich Gudat,*a   Denis Bubrin,a   Ingo Hartenbach,a   Thomas Schleid,a   Zoltán Benkőb  and  László Nyulászi*b  

* Corresponding authors

a Institut für Anorganische Chemie, Universität Stuttgart, Pfaffenwaldring 55, 70550 Stuttgart, Germany
E-mail: gudat@iac.uni-stuttgart.de
Fax: (+49) 711 685 64241

b Department of Inorganic and Analytical Chemistry, Budapest University of Technology and Economics, Szent Gellért tér 4, H-1111 Budapest
E-mail: nyulaszi@mail.bme.hu
Fax: (+36) 1 463-36-42

Abstract

Isoelectronic benzo-1,3,2-diazaphospholium cations and benzo-1,3,2-diazaphospholide anions were prepared from the same phosphazane precursor; both species display according to computational studies similar aromaticity as the neutral benzo-1,3,2-diazaphosphole but are chemically more stable due to their ionic nature.

Graphical abstract: Benzo-1,3,2-diazaphospholide and benzo-1,3,2-diazaphospholium: an isoelectronic aromatic anion–cation pair

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Article information

DOI
https://doi.org/10.1039/B817046K
Article type
Communication
Submitted
29 Sep 2008
Accepted
12 Nov 2008
First published
15 Dec 2008

Chem. Commun., 2009, 830-832

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Benzo-1,3,2-diazaphospholide and benzo-1,3,2-diazaphospholium: an isoelectronic aromatic anion–cation pair

D. Schmid, S. Loscher, D. Gudat, D. Bubrin, I. Hartenbach, T. Schleid, Z. Benkő and L. Nyulászi, Chem. Commun., 2009, 830 DOI: 10.1039/B817046K

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