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Chem. Commun., 2009, 3539 - 3541, DOI: 10.1039/b908167d


Combination of a binaphthol-derived phosphite and a C1-symmetric phosphinamine generates heteroleptic catalysts in Rh- and Pd-mediated reactions

Luca Pignataro, Benita Lynikaite, Raffaele Colombo, Stefano Carboni, Martin Krupika, Umberto Piarulli and Cesare Gennari


Heteroleptic complexes, formed selectively by using a 1 : 1 combination of a -donor and a -acceptor ligand, are involved in Rh- and Pd-catalysed reactions.

Graphical abstract image for this article  (ID: b908167d)