Issue 43, 2009
From the journal:

Chemical Communications

Skeletal rearrangement of all-carbon spiro skeletons mediated by a Lewis acid†

Fei Zhao,a   Chao Wang,a   Lantao Liu,ab   Wen-Xiong Zhanga  and  Zhenfeng Xi*ac  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China
E-mail: zfxi@pku.edu.cn
Fax: +86 10 62751708
Tel: +86 10 62759728

b Institute of Chemistry, Chinese Academy of Sciences, Beijing, China

c State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, China

Abstract

Mediated by AlCl3, substituted spiro[4.5]deca-tetraenes underwent novel and selective skeletal rearrangement to generate indene derivatives in high to excellent yields.

Graphical abstract: Skeletal rearrangement of all-carbon spiro skeletons mediated by a Lewis acid

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Article information

DOI
https://doi.org/10.1039/B914619A
Article type
Communication
Submitted
20 Jul 2009
Accepted
21 Aug 2009
First published
11 Sep 2009

Chem. Commun., 2009, 6569-6571

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Skeletal rearrangement of all-carbon spiro skeletons mediated by a Lewis acid

F. Zhao, C. Wang, L. Liu, W. Zhang and Z. Xi, Chem. Commun., 2009, 6569 DOI: 10.1039/B914619A

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