Issue 2, 2010
From the journal:

Chemical Communications

Flexible synthesis, structural determination, and synthetic application of a new C1-symmetric chiral ammonium betaine†

Daisuke Uraguchi,a   Kyohei Koshimotoa  and  Takashi Ooi*a  

* Corresponding authors

a Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Furo-cho B2-3(611), Chikusa, Nagoya 464-8603, Japan
E-mail: tooi@apchem.nagoya-u.ac.jp
Fax: +81-(0)52-789-3338
Tel: +81-(0)52-789-4501

Abstract

A C1-symmetric chiral ammonium betaine has been developed, and its intramolecular ion-pairing structure in solid state and its catalytic performance to achieve the highly stereoselective Mannich-type reaction of 2-alkoxythiazol-5(4H)-ones are revealed.

Graphical abstract: Flexible synthesis, structural determination, and synthetic application of a new C1-symmetric chiral ammonium betaine

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Article information

DOI
https://doi.org/10.1039/B916627K
Article type
Communication
Submitted
13 Aug 2009
Accepted
09 Nov 2009
First published
25 Nov 2009

Chem. Commun., 2010,46, 300-302

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Flexible synthesis, structural determination, and synthetic application of a new C1-symmetric chiral ammonium betaine

D. Uraguchi, K. Koshimoto and T. Ooi, Chem. Commun., 2010, 46, 300 DOI: 10.1039/B916627K

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