Issue 10, 2010
From the journal:

Chemical Communications

Platinum(ii)-catalyzed intermolecular hydroamination of monosubstituted allenes with secondary alkylamines†

Kristina L. Toupsa  and  Ross A. Widenhoefer*a  

* Corresponding authors

a French Family Science Center, Duke University, Durham, NC, USA
E-mail: rwidenho@chem.duke.edu
Fax: +1-919-6601605
Tel: +1-919-6601533

Abstract

A 1 ∶ 1 mixture of (dppf)PtCl2 and AgOTf (5 mol%) catalyzed the intermolecular hydroamination of monosubstituted allenes with secondary alkylamines at 80 °C to form allylic amines in good yield with selective formation of the E-diastereomer.

Graphical abstract: Platinum(ii)-catalyzed intermolecular hydroamination of monosubstituted allenes with secondary alkylamines

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Article information

DOI
https://doi.org/10.1039/B925859K
Article type
Communication
Submitted
08 Dec 2009
Accepted
06 Jan 2010
First published
16 Jan 2010

Chem. Commun., 2010,46, 1712-1714

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Platinum(II)-catalyzed intermolecular hydroamination of monosubstituted allenes with secondary alkylamines

K. L. Toups and R. A. Widenhoefer, Chem. Commun., 2010, 46, 1712 DOI: 10.1039/B925859K

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