Design and understanding of solid-state and crystalline materials
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Paper
CrystEngComm, 2009, 11, 2452 - 2455, DOI: 10.1039/b902936m
A new 3-D two-fold interpenetrated framework with sqp net based on Cu6I6 and Cu8I8 cluster nodes
Qin Hou, Jie-Hui Yu, Jia-Ning Xu, Qing-Feng Yang and Ji-Qing Xu
With Cu6I6 and Cu8I8 clusters as 5-connected nodes, a new 3-D network [Cu14I14 (dabco)5(py)] (1) (dabco = 1,4-diazabicyclo[2.2.2]octane, py = pyridine) with a two-fold interpenetrated sqp-(44.66) topology has been hydrothermally synthesized. The solid-state luminescence spectrum displays a strong yellow-light emission with
max = 591 nm at room temperature.
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