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Physical Chemistry Chemical Physics

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10th Anniversary Article: 70 years of Landau-Teller theory for collisional energy transfer


19 March 2008

PCCP's latest 10th Anniversary Article is a Perspective article that, in historical retrospective, describes the development of the celebrated Landau-Teller (LT) model of 1936 for vibrational-translational energy exchange in collisions of an atom with a diatomic molecule. The article goes on the exemplify the usefulness of this approach to this day. 

Juergen Troe
Juergen Troe
The article was written by Juergen Troe and Evgueni Nikitin. Juergen Troe is professor of physical chemistry at Göttingen University and director at the Max-Planck Institute for Biophysical Chemistry at Göttingen, both in Germeny. He is currently a member of the PCCP Advisory board and has previously served as Chair of the PCCP Editorial Board. 

Troe is a prolific PCCP author and keen supporter of the journal. 'Several of our articles appeared in PCCP, the journal which is so close to my heart since my days as Editorial Chairman. With delight I saw PCCP growing up to its present stunning success,' he said. 

Troe and Nikitin have worked together over a number of years. 'The present retrospective from Nikitin's side is an homage to the great Landau and includes a series of improvements which make collisional energy transfer theory more correct and more "understandable". From my side, it is a testimony for more than 40 years of friendship and most enjoyable collaboration with Nikitin,' said Troe. 

 

Link to journal article

70 years of Landau–Teller theory for collisional energy transfer. Semiclassical three-dimensional generalizations of the classical collinear model
E. E. Nikitin and J. Troe, Phys. Chem. Chem. Phys., 2008, 10, 1483
DOI: 10.1039/b715095d

Also of interest

Restoring detailed balance in the Landau–Teller probabilities for collision-induced vibrational transitions
E. E. Nikitin and J. Troe, Phys. Chem. Chem. Phys., 2006, 8, 2012
DOI: 10.1039/b517843f

Low temperature capture of open shell dipolar molecules by ions: the capture of rotationally selected NO(21/2, j) by C+
E. I. Dashevskaya, I. Litvin, E. E. Nikitin and J. Troe, Phys. Chem. Chem. Phys., 2007, 9, 1559
DOI: 10.1039/b615826a

Modelling low-energy electron–molecule capture processes
E. I. Dashevskaya, I. Litvin, E. E. Nikitin and J. Troe, Phys. Chem. Chem. Phys., 2008, 10, 1270
DOI: 10.1039/b713530k