Issue 1, 1999
From the journal:

Journal of the Chemical Society, Dalton Transactions

Coupling and disproportionation reactions of ethyne on ruthenium carbonyl clusters: molecular structures of Ru5(µ4-CHCHCCH2)(CO)15 and Ru6(µ-H)(µ4-C)(µ4-CCMe)(µ-CO)(CO)16†

Michael I. Bruce,   Brian W. Skelton,   Allan H. White  and  Natasha N. Zaitseva  

Abstract

Thermolysis of Ru3(µ3-C2H2)(µ-CO)(CO)9 1 (50 °C, 6 h) has given Ru5(µ4-CHCHCCH2)(CO)15 3 and Ru6(µ-H)(µ4-C)(µ4-CCMe)(µ-CO)(CO)16 4, both characterised by X-ray crystallography; in 3, coupling of two ethyne molecules occurred, likely with prior isomerisation of one to vinylidene, whereas in 4, two molecules of ethyne disproportionate to carbide and methylethynyl.

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DOI
https://doi.org/10.1039/A807781I
Article type
Paper

J. Chem. Soc., Dalton Trans., 1999, 13-14

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Coupling and disproportionation reactions of ethyne on ruthenium carbonyl clusters: molecular structures of Ru5(µ4-CHCHCCH2)(CO)15 and Ru6(µ-H)(µ4-C)(µ4-CCMe)(µ-CO)(CO)16†

M. I. Bruce, B. W. Skelton, A. H. White and N. N. Zaitseva, J. Chem. Soc., Dalton Trans., 1999, 13 DOI: 10.1039/A807781I

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