Issue 19, 2000
From the journal:

Journal of the Chemical Society, Dalton Transactions

A novel chiral distibine-centred polyimido anion

Simon J. Coles,a   Michael B. Hursthouse,a   Jonathan S. Joya  and  Michael A. Paver*a  

* Corresponding authors

a Department of Chemistry, University of Southampton, Highfield, Southampton, UK
E-mail: m.a.paver@soton.ac.uk

Abstract

Reaction of (Me2N)2Sb(CH2)3Sb(NMe2)2 with 4 equivalents of 2-NHLiPy (Py = pyridyl) generates the novel distibine-centred dianion complex 1,3-[(RNLi)Sb]2(μ-NR)(CH2)3·(RNHLi)·3THF (1), incorporating the co-complexation of primary lithium amide; the X-ray crystal structure of 1 reveals a bimetallic imido-/amido-bridged cage structure of interlocking 6-membered rings, crystallising as a single enantiomer.

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Article information

DOI
https://doi.org/10.1039/B007031I
Article type
Communication
Submitted
30 Aug 2000
Accepted
30 Aug 2000
First published
15 Sep 2000

J. Chem. Soc., Dalton Trans., 2000, 3239-3241

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A novel chiral distibine-centred polyimido anion

S. J. Coles, M. B. Hursthouse, J. S. Joy and M. A. Paver, J. Chem. Soc., Dalton Trans., 2000, 3239 DOI: 10.1039/B007031I

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