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Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry



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Dalton Trans., 2007, 5369 - 5371, DOI: 10.1039/b711804j

A template-directed synthetic approach to halogen-bridged mixed-valence platinum complexes on artificial peptides in solution

Kentaro Tanaka, Kenji Kaneko, Yusuke Watanabe and Mitsuhiko Shionoya

A template-directed synthetic approach to halogen-bridged mixed-valence platinum complexes has been performed in organic media using, for instance, a synthetic peptide bearing two bis(ethylenediamine)-based Pt(IV) complexes with two axial bromide anionic ligands, [ 1a(Pt(IV)Br2(en))2](RSO3)4, and a [Pt(II)(en)2](RSO3)2 complex (R = (C12H25OCH2)2CHO(CH2)3–).

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