Selective carbon–carbon bond cleavage of 2,2′-dibromotolanevia photolysis of its appropriate (diphosphine)Pt0 complex in the solid state

Holm Petzold; Thomas Weisheit; Helmar Görls; Hergen Breitzke; Gerd Buntkowsky; Daniel Escudero; Leticia González; Wolfgang Weigand

doi:10.1039/B801230J

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Selective carbon–carbon bond cleavage of 2,2′-dibromotolanevia photolysis of its appropriate (diphosphine)Pt⁰ complex in the solid state†

Holm Petzold,^a Thomas Weisheit,^a Helmar Görls,^a Hergen Breitzke,^b Gerd Buntkowsky,^b Daniel Escudero,^b Leticia González^b and Wolfgang Weigand*^a

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* Corresponding authors

^a Institut für Anorganische und Analytische Chemie, Friedrich-Schiller-Universität, Jena, Germany
E-mail: c8wewo@uni-jena.de
Fax: +49-3641-948102
Tel: +49-3641-948160

^b Institut für Physikalische Chemie, Friedrich-Schiller-Universität, Jena, Germany

Abstract

By irradiating crystals of a (diphosphine)Pt⁰ complex containing 2,2′-dibromotolane as ligand with sunlight, a rare example of selective carbon–carbon bond cleavage in the solid state could be observed.

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Article information

DOI: https://doi.org/10.1039/B801230J
Article type: Communication
Submitted: 22 Jan 2008
Accepted: 28 Jan 2008
First published: 20 Feb 2008

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Dalton Trans., 2008, 1979-1981

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Selective carbon–carbon bond cleavage of 2,2′-dibromotolanevia photolysis of its appropriate (diphosphine)Pt⁰ complex in the solid state

H. Petzold, T. Weisheit, H. Görls, H. Breitzke, G. Buntkowsky, D. Escudero, L. González and W. Weigand, Dalton Trans., 2008, 1979 DOI: 10.1039/B801230J

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Dalton Transactions