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Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry



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Dalton Trans., 2009, 8828 - 8830, DOI: 10.1039/b914573g

On the mechanism of isospecific epoxide polymerization by salen cobalt(III) complexes: Evidence for solid-state catalysis

Hiroharu Ajiro, Kathryn L. Peretti, Emil B. Lobkovsky and Geoffrey W. Coates

Mechanistic studies have revealed that the isospecific polymerization of epoxides by a discrete salen cobalt(III) catalyst occurs at the surface of the undissolved, crystalline complex.

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