Volume 141, 2009

“Similarities” between confined and supercooled water

Abstract

Neutron diffraction and deep inelastic neutron scattering experiments performed on bulk stable and supercooled water are compared with the same experiments performed on water confined in silica substrates. Similarities and differences between the two cases clearly show up, as far as both microscopic structure and single proton dynamics are concerned. In particular in both supercooled bulk water and water under confinement we observe a closer average distance between first neighboring oxygen sites and shortening of the H-bonds. In contrast the number of H-bonds per molecule and the number of interstitial water molecules are severely reduced under confinement, and the second peak of the oxygen-oxygen radial distribution function is shifted to shorter distances, compared to the bulk phase. Based on these results a possible scenario for understanding changes evidenced by deep inelastic neutron scattering when water is either confined or supercooled is proposed.

Article information

Article type
Paper
Submitted
04 Apr 2008
Accepted
16 May 2008
First published
09 Sep 2008

Faraday Discuss., 2009,141, 347-358

“Similarities” between confined and supercooled water

M. A. Ricci, F. Bruni and A. Giuliani, Faraday Discuss., 2009, 141, 347 DOI: 10.1039/B805706K

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