Issue 14, 1995
From the journal:

Journal of the Chemical Society, Faraday Transactions

Oxidation of a tricoordinated CuI complex to a tetracoordinated CuII species. A single- EPR study

Cornelia Palivan,   Théo Berclaz,   Michel Geoffroy,   Sundara Ramaprabhu  and  Gérald Bernardinelli  

Abstract

Bis(N-methylimidazolidinethi-2-one)copper(I) chloride has been synthesized and its crystal structure determined. X-Irradiation of a single crystal of this compound leads to the formation of a CuII complex which was studied by EPR: it was shown that this species results from the addition of a radiogenic Cl atom on the CuI precursor. The structural changes induced by this reaction are revealed by the g-tensor and by the hyperfine tensors of one copper and two chlorine nuclei. The structure of this S2Cl2Cu type complex was compared with other sulfur- or chlorine-containing CuII complexes.

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Article information

DOI
https://doi.org/10.1039/FT9959102155
Article type
Paper

J. Chem. Soc., Faraday Trans., 1995,91, 2155-2160

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Oxidation of a tricoordinated CuI complex to a tetracoordinated CuII species. A single- EPR study

C. Palivan, T. Berclaz, M. Geoffroy, S. Ramaprabhu and G. Bernardinelli, J. Chem. Soc., Faraday Trans., 1995, 91, 2155 DOI: 10.1039/FT9959102155

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