Issue 9, 2009
From the journal:

Green Chemistry

Catalytic dechlorination of polychlorinated biphenyls (PCBs) using amine functionalised titanocenes†

Andrew E.D. Fletcher,a   Jonathan D. Hyatt,a   Kang Min Ok‡a  and  Dermot O'Hare*a  

* Corresponding authors

a Chemistry Research Laboratory, Department of Chemistry, University of Oxford, Mansfield Road, Oxford, UK
E-mail: dermot.ohare@chem.ox.ac.uk
Fax: +44 1865 272690
Tel: +44 1865 272686

Abstract

Novel ring-functionalised titanocene dichloride compounds have been prepared and tested for catalytic activity for the dechlorination of polychlorinated biphenyls (PCBs) under Schwartz conditions; they represent the first examples of metal complexes that are active under these conditions without the need for toxic additives, such as pyridine.

Graphical abstract: Catalytic dechlorination of polychlorinated biphenyls (PCBs) using amine functionalised titanocenes

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Article information

DOI
https://doi.org/10.1039/B906311K
Article type
Paper
Submitted
31 Mar 2009
Accepted
08 Jun 2009
First published
29 Jun 2009

Green Chem., 2009,11, 1343-1348

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Catalytic dechlorination of polychlorinated biphenyls (PCBs) using amine functionalised titanocenes

A. E.D. Fletcher, J. D. Hyatt, K. M. Ok and D. O'Hare, Green Chem., 2009, 11, 1343 DOI: 10.1039/B906311K

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