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Paper
Green Chem., 2009, 11, 1832 - 1846, DOI: 10.1039/b915290n
Low catalyst loading ligand-free palladium-catalyzed direct arylation of furans: an economically and environmentally attractive access to 5-arylfurans
Jia Jia Dong, Julien Roger, Franc Po
gan and Henri Doucet
The direct 5-arylation of furans at very low catalyst loading using Pd(OAc)2 as catalyst without added ligand proceed in high yields. Turnover numbers up to 10000 have been obtained for the coupling of several activated aryl bromides. A wide range of functions on the furan or aryl bromide is tolerated.

