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Annual Reports on the Progress of Chemistry Section A (Inorganic Chemistry)

Section A reviews annual developments in inorganic and bioinorganic chemical research




Review

Annu. Rep. Prog. Chem., Sect. A: Inorg. Chem. , 2005, 101, 231 - 252, DOI: 10.1039/b410395p


14  Copper

D. W. Smith


Highlights of this year's literature include the characterisation of [CuMe], the first diazene-bridged dicopper(I) complex, and illumination of dioxygen binding by dicopper(I) complexes. The observation of {Cu(2-H2)}+ species has been a major development in studies of copper-exchanged zeolites. Among polynuclear copper(II) species, examples of square planar µ4-bridging hydroxide and trigonal planar µ3-chloride are remarkable.