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Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Journal of the Chemical Society A: Inorganic, Physical, Theoretical was published from 1966 - 1971.

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Paper

J. Chem. Soc. A, 1971, 44 - 48, DOI: 10.1039/J19710000044


Kinetics of reactions of Schiff-base complexes of iron(II). Part IV. Reaction of tris-[-(2-pyridyl)benzylideneaniline]iron(II) complexes with cyanide in aqueous alcohols

J. Burgess, G. E. Ellis, D. J. Evans, A. Porter, R. Wane and R. D. Wyvill


Kinetics of reaction of tris-[-(2-pyridyl)benzylideneaniline]iron(II) complexes with cyanide in a range of aqueous alcohols indicate a bimolecular reaction mechanism. Second-order rate constants correlate with rate constants for aquation of the respective complexes, and with Grunwald–Winstein solvent Y values.