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Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Journal of the Chemical Society A: Inorganic, Physical, Theoretical was published from 1966 - 1971.

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Paper

J. Chem. Soc. A, 1971, 143 - 145, DOI: 10.1039/J19710000143


Reaction of 2,2,6,6-tetramethylheptane-3,5-dione with hexachlorodipalladate ion

D. A. White


The formation of bis-(2,2,6,6-tetramethylheptane-3,5-dionato)palladium by reaction of the -diketone with disodium hexachlorodipalladate in methanol appears to involve the intermediate formation of di-µ-methoxy-bis-(2,2,6,6-tetramethylheptane-3,5-dionato)dipalladium. Under suitable conditions this compound becomes the sole product and it has been isolated and characterized.