Journal of the Chemical Society A: Inorganic, Physical, Theoretical
Journal of the Chemical Society A: Inorganic, Physical, Theoretical was published from 1966 - 1971.
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Paper
J. Chem. Soc. A, 1971, 182 - 183, DOI: 10.1039/J19710000182
Proton resonance studies of the Schlenk equilibria for methyl- and ethyl-zinc iodide in tetrahydrofuran
D. F. Evans and G. V. Fazakerley
Proton resonance spectra are reported for mixtures of methyl- and ethyl-zinc iodide with the corresponding bisalkylzincs in tetrahydrofuran solution. At low temperatures, alkyl exchange is slow on a proton resonance timescale. For the Schlenk equilibria R2Zn + Znl2
2RZnl K is ? 500 at –70 °C, in agreement with previous results.
