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Journal of Chemical Research

From January 2000, the monthly Journal of Chemical Research has been owned and published by Science Reviews Ltd.




Paper

J. Chem. Res. (S), 1999, 136 - 137, DOI: 10.1039/a805058i


Synthesis of 5-(2-Phenylethenyl)indolizines by Selective Intermolecular 1,3-Dipolar Cycloaddition of 2-(2-Phenylethenyl)pyridinium N-Ylide with Alkenes Promoted by Tetrakis-pyridine Cobalt(II) Dichromate

Jian Zhou, Yuefei Hu and Hongwen Hu


Intermolecular 1,3-dipolar cycloadditions of 2-(2-phenylethenyl)pyridinium N-ylides (3ad) with electron-deficient alkenes (5ad) were carried out selectively in the presence of tetrakis-pyridine cobalt(II) dichromate to yield 5-(2-phenylethenyl)indolizines (6aj) in moderate yields (48–63%).