Paper

J. Chem. Res. (S), 1999, 108 - 109, DOI: 10.1039/a807128d

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Stereoselective Thallium-induced Ring Contraction of Glycals

Dana H. Braithwaite, CedricW. Holzapfel and D. Bradley G. Williams

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Various glycals, treated with Tl(NO₃)₃·3H₂O under mild conditions in an acetonitrile–methanol solvent mixture, underwent ring contraction in a stereoselective fashion, affording stable acetal products.

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