Paper

J. Chem. Res. (S), 1999, 146 - 147, DOI: 10.1039/a808311h

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Kinetic Isotope Effects in the Chromium(VI) Oxidation of Bicyclic Alcohols

J. Hodge Markgraf, Jordan S. Dubow, Jessica A. Charland and Elliott H. Sohn

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Pseudo first-order rate constants are determined for the oxidation of a series of secondary alcohols and their monodeutero analogues by ammonium chromate in aqueous acidic solution at several temperatures; the relative rates and activation parameters are consistent with a cyclic, symmetrical transition state.

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