Issue 37, 2005

In situ CCVD synthesis of carbon nanotubes within a commercial ceramic foam

Abstract

Consolidated nanocomposite foams containing a large quantity of carbon nanotubes (CNTs) within millimetre-sized pores are prepared for the first time. A commercial ceramic foam is impregnated by a 60 g L−1 slurry of a (Mg(1−x)(Co0.75Mo0.25)xO solid solution (x = 0.01, 0.05, 0.1 and 0.2) powder in ethanol. Three successive impregnations led to deposits several tens of µm thick, with a good coverage of the commercial-ceramic pore walls but without closing the pores. The materials were submitted to a CCVD treatment in H2–CH4 atmosphere in order to synthesise the CNTs. When using attrition-milled powders, the carbon is mostly in the form of nanofibres or disordered carbon rather than CNTs. Using non-milled powders produces a less-compact deposit of catalytic material with a higher adherence to the walls of the ceramic foam. After CCVD, the carbon is mostly in the form of high-quality CNTs, as when using powder beds, their quantity being 2.5 times higher. The so-obtained consolidated nanocomposite materials show a multi-scale pore structuration.

Graphical abstract: In situ CCVD synthesis of carbon nanotubes within a commercial ceramic foam

Article information

Article type
Paper
Submitted
22 Apr 2005
Accepted
06 Jul 2005
First published
02 Aug 2005

J. Mater. Chem., 2005,15, 4041-4050

In situ CCVD synthesis of carbon nanotubes within a commercial ceramic foam

A. Cordier, E. Flahaut, C. Viazzi, C. Laurent and A. Peigney, J. Mater. Chem., 2005, 15, 4041 DOI: 10.1039/B505654C

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