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J. Mater. Chem., 2007, 17, 52 - 55, DOI: 10.1039/b613887j


DNA-mediated assembly of iron platinum (FePt) nanoparticles

Sudhanshu Srivastava, Bappaditya Samanta, Palaniappan Arumugam, Gang Han and Vincent M. Rotello


Nanocomposite materials consisting of FePt nanoparticles and DNA were constructed via DNA-mediated bricks and mortar self-assembly. Electrostatic interaction between the cationic nanoparticles and the DNA through surface recognition led to the formation of extended composite aggregates. These DNA-assembled aggregates feature increased interparticle spacing arising from the DNA mortar. The enhanced structure and increased spacing in the bio-nanocomposite assembly was found to alter the magnetic properties of the assemblies, as demonstrated by a 54 K change in blocking temperature (TB).

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