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Org. Biomol. Chem., 2009, 7, 4166 - 4168, DOI: 10.1039/b916027m

Bypassing stereoselectivity in the early steps of alkaloid biosynthesis

Peter Bernhardt, Nancy Yerkes and Sarah E. O'Connor

Total synthesis of glycosylated seco-iridoid stereoisomers allows the identification and bypassing of the stereoselectivity of early steps in monoterpene indole alkaloid biosynthesis.

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